For Windows 10 if you want use pip in normal cmd, not only in Anaconda prompt. you need add 3 environment paths. like the followings:
D:\Anaconda3
D:\Anaconda3\Scripts
D:\Anaconda3\Library\bin
most people only add D:\Anaconda3\Scripts
Reference
https://stackoverflow.com/questions/45954528/pip-is-configured-with-locations-that-require-tls-ssl-however-the-ssl-module-in
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